Role of additives in silica-supported polyethylenimine adsorbents for CO2 adsorption
نویسندگان
چکیده
منابع مشابه
Oxidative degradation of silica-supported polyethylenimine for CO2 adsorption: insights into the nature of deactivated species.
The oxidative degradation of polyethylenimine-impregnated mesoporous SBA-15 silica for CO2 capture was investigated at the molecular level. The adsorbents were exposed to flowing air at different temperatures, and their degree of deactivation was evaluated through the measurement of CO2 adsorption capacity prior and subsequent to air exposure. A solvent-extraction method was employed to isolate...
متن کاملTransport, Zwitterions, and the Role of Water for CO2 Adsorption in Mesoporous Silica-Supported Amine Sorbents
The uptake of CO2 in highly loaded, silica-supported, polyethylenimine (PEI)-impregnated sorbents was investigated in a reaction-diffusion model of the CO2 adsorption process. The model successfully replicated the pseudoequilibrium behavior experimentally observed in thermogravimetry (TGA) experiments. A parametric study and sensitivity analysis of the model revealed that the stability and mobi...
متن کاملOptimal Surface Amino-Functionalization Following Thermo-Alkaline Treatment of Nanostructured Silica Adsorbents for Enhanced CO2 Adsorption
Special preparation of Santa Barbara Amorphous (SBA)-15, mesoporous silica with highly hexagonal ordered, these materials have been carried out for creating adsorbents exhibiting an enhanced and partially selective adsorption toward CO₂. This creation starts from an adequate conditioning of the silica surface, via a thermo-alkaline treatment to increase the population of silanol species on it. ...
متن کاملChromatographic Characterization of Adsorption Properties of Carbon and Silica Adsorbents
Adsorption isotherms and specific retention volumes of benzene on MCM41C16 mesoporous silica and F4O porous carbon were determined at different temperatures by employing inverse gas chromatography. The differential isosteric enthalpies, -∆Hads , and entropies, -∆Sads , of adsorption were calculated from the retention time data and compared with the results obtained from the adsorption second vi...
متن کاملNovel Silica-Based Hybrid Adsorbents: Lead(II) Adsorption Isotherms
Water pollution caused by the lead(II) from the spent liquor has caught much attention. The research from the theoretical model to application fundaments is of vital importance. In this study, lead(II) adsorption isotherms are investigated using a series of hybrid membranes containing mercapto groups (-SH groups) as the hybrid adsorbents. To determine the best fitting equation, the experimental...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: Materials Research Express
سال: 2020
ISSN: 2053-1591
DOI: 10.1088/2053-1591/ab80eb